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Graphene has many unusual properties. It is the strongest material ever tested,4 efficiently conducts heat and electricity and is nearly transparent. Graphene shows a large and nonlinear diamagnetism,5 which is greater than that of graphite, and can be levitated by neodymium magnets. Scientists theorized about graphene for years. It had been unintentionally produced in small quantities for centuries, through the use of pencils and other similar graphite applications. It was originally observed in electron microscopes in 1. The material was later rediscovered, isolated, and characterized in 2. Andre Geim and Konstantin Novoselov at the University of Manchester. Research was informed by existing theoretical descriptions of its composition, structure, and properties. This work resulted in the two winning the Nobel Prize in Physics in 2. DefinitioneditGraphene is a combination of graphite and the suffix ene, named by Hanns Peter Boehm,1. The term graphene first appeared in 1. GICs conceptually a GIC is a crystalline salt of the intercalant and graphene. The term was also used in early descriptions of carbon nanotubes,1. PAH. 1. 5 Graphene can be considered an infinite alternant only six member carbon ring polycyclic aromatic hydrocarbon. The International Union of Pure and Applied Chemistry notes previously, descriptions such as graphite layers, carbon layers, or carbon sheets have been used for the term graphene. The term graphene should be used only when the reactions, structural relations or other properties of individual layers are discussed. Geim defined isolated or free standing graphene as graphene is a single atomic plane of graphite, which  and this is essential  is sufficiently isolated from its environment to be considered free standing. This definition is narrower than the IUPAC definition and refers to cloven, transferred and suspended graphene. Other forms such as graphene grown on various metals, can become free standing if, for example, suspended or transferred 1. Si. O2 or silicon carbide. StructureeditGraphene is a crystallineallotrope of carbon with 2 dimensional properties. Its carbon atoms are densely packed in a regular atomic scale chicken wire hexagonal pattern. Each atom has four bonds, one bond with each of its three neighbors and one bond that is oriented out of plane. The atoms are about 1. Graphenes hexagonal lattice can be regarded as two interleaving triangular lattices. This perspective was successfully used to calculate the band structure for a single graphite layer using a tight binding approximation. Graphenes stability is due to its tightly packed carbon atoms and a sp. The final pz electron makes up the bond. The bonds hybridize together to form the band and bands. These bands are responsible for most of graphenes notable electronic properties, via the half filled band that permits free moving electrons. Graphene sheets in solid form usually show evidence in diffraction for graphites 0. This is true of some single walled nanostructures. However, unlayered graphene with only hk. TEM studies show faceting at defects in flat graphene sheets2. Graphene can self repair holes in its sheets, when exposed to molecules containing carbon, such as hydrocarbons. Bombarded with pure carbon atoms, the atoms perfectly align into hexagons, completely filling the holes. The atomic structure of isolated, single layer graphene was studied by TEM on sheets of graphene suspended between bars of a metallic grid. Electron diffraction patterns showed the expected honeycomb lattice. Suspended graphene showed rippling of the flat sheet, with amplitude of about one nanometer. These ripples may be intrinsic to the material as a result of the instability of two dimensional crystals,2. TEM images of graphene. Atomic resolution real space images of isolated, single layer graphene on Si. O2 substrates are available3. STM. Photoresist residue, which must be removed to obtain atomic resolution images, may be the adsorbates observed in TEM images, and may explain the observed rippling. Rippling on Si. O2 is caused by conformation of graphene to the underlying Si. O2 and is not intrinsic. StabilityeditAb initio calculations show that a graphene sheet is thermodynamically unstable if its size is less than about 6. AnalogseditAnalogs3. Analogs can be systems in which the physics is easier to observe and to manipulate. In those systems, electrons are not always the chosen particlesthey might be optical photons,3. Also, the honeycomb structure in which those particles evolve can be of a different nature than carbon atoms in graphene. It can be, respectively, a photonic crystal, an array of metallic rods, metallic nanoparticles, a lattice of coupled microcavities or an optical lattice. PropertieseditGraphene has a theoretical specific surface area SSA of 7. This is much larger than that reported to date for carbon black typically smaller than 7. CNTs, from 1. 00 to 7. ElectroniceditGNRband structure for zig zag orientation. Tightbinding calculations show that zig zag orientation is always metallic. GNRband structure for armchair orientation. Tightbinding calculations show that armchair orientation can be semiconducting or metallic depending on width chirality. Graphene is a zero gap semiconductor, because its conduction and valence bands meet at the Dirac points, which are six locations in momentum space, on the edge of the Brillouin zone, divided into two non equivalent sets of three points. The two sets are labeled K and K. The sets give graphene a valley degeneracy of gv 2. By contrast, for traditional semiconductors the primary point of interest is generally, where momentum is zero. However, if the in plane direction is confined, in which case it is referred to as a nanoribbon, its electronic structure is different. If it is zig zag, the bandgap is zero. If it is armchair, the bandgap is non zero see figure. Graphene displays remarkable electron mobility at room temperature, with reported values in excess of 7. V1s1. Hole and electron mobilities were expected to be nearly identical. The mobility is nearly independent of temperature between 7. K and 7. 00. 21. 00. K,4. 14. 24. Scattering by graphenes acoustic phonons intrinsically limits room temperature mobility to 7. V1s1 at a carrier density of 7. The corresponding resistivity of graphene sheets would be 6. This is less than the resistivity of silver, the lowest otherwise known at room temperature. However, on Si. O2 substrates, scattering of electrons by optical phonons of the substrate is a larger effect than scattering by graphenes own phonons. This limits mobility to 7. V1s1. 4. 3 Charge transport is affected by adsorption of contaminants such as water and oxygen molecules. This leads to non repetitive and large hysteresis I V characteristics.